Difference between revisions of "TSMFK01"

From relax wiki
Jump to navigation Jump to search
(→‎Links: Updated the HTML manual link.)
(→‎See also: Added more categories.)
 
(3 intermediate revisions by the same user not shown)
Line 1: Line 1:
−
= Intro =
+
This is the model for 2-site very-slow exchange model for time scales within range of microsecond to second time scale, where {{:pA}} ≫ {{:pB}}, and named after Tollinger et al. (2001).  This model is labelled as '''TSMFK01''' in [[Relaxation dispersion citation for relax|relax]].  A particularly interesting feature of the dispersion curves is the damped oscillations, which occur at low CPMG field strengths, and is solely a function of the chemical shift difference between the two sites (i.e., independent of the rate of exchange).
−
This is the model for 2-site very-slow exchange model for time scales within range of microsecond to second time scale, where $p_A \gg p_B$, and named after Tollinger et al. (2001).  This model is labelled as '''TSMFK01''' in [[Relaxation dispersion citation for relax|relax]].  A particularly interesting feature of the dispersion curves is the damped oscillations, which occur at low CPMG field strengths, and is solely a function of the chemical shift difference between the two sites (i.e., independent of the rate of exchange).
 
  
 
== Parameters ==
 
== Parameters ==
  
−
The TSMFK01 model has the parameters {$R_{2A}^0$, $...$, $\Delta\omega$, $k_{AB}$}.
+
The TSMFK01 model has the parameters {{{:R2Azero}}, ..., {{:Deltaomega}}, {{:kAB}}}.
  
 
== Reference ==
 
== Reference ==
Line 10: Line 9:
 
The reference for the TSMFK01 model is:
 
The reference for the TSMFK01 model is:
  
−
* Tollinger, M., Skrynnikov, N. R., Mulder, F. A. A., Forman-Kay, J. D., and Kay, L. E. (2001).  Slow dynamics in folded and unfolded states of an sh3 domain. ''J. Am. Chem. Soc.'', '''123'''(46), 11341-11352. ([http://dx.doi.org/10.1021/ja011300z 10.1021/ja011300z])
+
* {{#lst:Citations|Tollinger01}}
  
 
== Links ==
 
== Links ==
Line 20: Line 19:
  
 
== See also ==
 
== See also ==
 +
[[Category:Models]]
 +
[[Category:Dispersion models]]
 
[[Category:Relaxation dispersion analysis]]
 
[[Category:Relaxation dispersion analysis]]

Latest revision as of 16:47, 6 November 2015

This is the model for 2-site very-slow exchange model for time scales within range of microsecond to second time scale, where pA ≫ pB, and named after Tollinger et al. (2001). This model is labelled as TSMFK01 in relax. A particularly interesting feature of the dispersion curves is the damped oscillations, which occur at low CPMG field strengths, and is solely a function of the chemical shift difference between the two sites (i.e., independent of the rate of exchange).

Parameters

The TSMFK01 model has the parameters {R2A0, ..., Δω, kAB}.

Reference

The reference for the TSMFK01 model is:

  • Tollinger, M., Skrynnikov, N. R., Mulder, F. A. A., Forman-Kay, J. D., and Kay, L. E. (2001). Slow dynamics in folded and unfolded states of an sh3 domain. J. Am. Chem. Soc., 123(46), 11341-11352. (DOI: 10.1021/ja011300z)

Links

The implementation of the TSMFK01 model in relax can be seen in the:

See also