Difference between revisions of "TSMFK01"

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== See also ==
 
== See also ==
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[[Category:Models]]
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[[Category:Dispersion models]]
 
[[Category:Relaxation dispersion analysis]]
 
[[Category:Relaxation dispersion analysis]]

Latest revision as of 16:47, 6 November 2015

This is the model for 2-site very-slow exchange model for time scales within range of microsecond to second time scale, where pA ≫ pB, and named after Tollinger et al. (2001). This model is labelled as TSMFK01 in relax. A particularly interesting feature of the dispersion curves is the damped oscillations, which occur at low CPMG field strengths, and is solely a function of the chemical shift difference between the two sites (i.e., independent of the rate of exchange).

Parameters

The TSMFK01 model has the parameters {R2A0, ..., Δω, kAB}.

Reference

The reference for the TSMFK01 model is:

  • Tollinger, M., Skrynnikov, N. R., Mulder, F. A. A., Forman-Kay, J. D., and Kay, L. E. (2001). Slow dynamics in folded and unfolded states of an sh3 domain. J. Am. Chem. Soc., 123(46), 11341-11352. (DOI: 10.1021/ja011300z)

Links

The implementation of the TSMFK01 model in relax can be seen in the:

See also