Difference between revisions of "No Rex"
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(→Equation for No Exchange in R1rho: Switched to parameter templates for R1.) |
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| − | The relaxation dispersion model for no chemical exchange. This if for all [[SQ CPMG-type data]], [[MMQ CPMG-type data]], and [[R1rho-type data]]. This model is labelled as '''No Rex''' in relax. | + | The relaxation dispersion model for no chemical exchange. This if for all [[SQ CPMG-type data]], [[:Category:MMQ CPMG data|MMQ CPMG-type data]], and [[R1rho-type data]]. This model is labelled as '''No Rex''' in [[Relaxation dispersion citation for relax|relax]]. |
== Parameters == | == Parameters == | ||
| − | The No Rex model has the parameter | + | The No Rex model has the parameter {{:R2zero}} or {{:R1rhoprime}} depending on the data type. |
| + | |||
| + | == Equation for No Exchange in CPMG== | ||
| + | <math> | ||
| + | R_{2,\textrm{eff}} = R_2^0 | ||
| + | </math> | ||
| + | |||
| + | == Equation for No Exchange in R1rho== | ||
| + | <math> | ||
| + | \mathrm{R}_{1\rho}= \mathrm{R}_1\cos^2\theta + \mathrm{R}_{1\rho}{´} \sin^2\theta | ||
| + | </math> | ||
| + | |||
| + | If no {{:R1}} values has been loaded, but the <code>R1_fit</code> flag has been turned on, the {{:R1}} will be fitted as well. | ||
| + | |||
| + | For data without a loaded offset, (see also [[Relax_disp.spin_lock_offset%2Bfield | relax disp.spin lock offset+field]] ), if <br> | ||
| + | <math> | ||
| + | \bar{\Omega}_{S,i} = 0.0 | ||
| + | </math> | ||
| + | then the Rotating frame tilt angle θ is set to: | ||
| + | <math> | ||
| + | \theta = \frac{\pi}{2} | ||
| + | </math> | ||
| + | |||
| + | and as such <br> | ||
| + | <math> | ||
| + | cos^2\theta = cos^2\left( \frac{\pi}{2} \right) = 0.0 | ||
| + | </math> | ||
| + | |||
| + | Therefore the fitted {{:R1}} values have no meaning for "No Rex" model, if there is no offset. <br> | ||
== Reference == | == Reference == | ||
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== Links == | == Links == | ||
| − | The implementation of the No Rex model in relax can be seen in the: | + | The [[Relaxation dispersion citation for relax|implementation of the No Rex model in relax]] can be seen in the: |
| − | * [http://www.nmr-relax.com/manual/ | + | * [http://www.nmr-relax.com/manual/The_model_for_no_chemical_exchange_relaxation.html relax manual], |
* [http://www.nmr-relax.com/api/3.1/target_functions.relax_disp.Dispersion-class.html#func_NOREX API documentation], | * [http://www.nmr-relax.com/api/3.1/target_functions.relax_disp.Dispersion-class.html#func_NOREX API documentation], | ||
| − | * [http://www.nmr-relax.com/analyses/relaxation_dispersion.html relaxation dispersion page of the relax website]. | + | * [http://www.nmr-relax.com/analyses/relaxation_dispersion.html#No_Rex relaxation dispersion page of the relax website]. |
== See also == | == See also == | ||
| − | [[Category:Relaxation_dispersion]] | + | [[Category:Models]] |
| + | [[Category:Dispersion models]] | ||
| + | [[Category:Relaxation_dispersion analysis]] | ||
Latest revision as of 17:05, 18 November 2015
The relaxation dispersion model for no chemical exchange. This if for all SQ CPMG-type data, MMQ CPMG-type data, and R1rho-type data. This model is labelled as No Rex in relax.
Contents
Parameters
The No Rex model has the parameter R20 or R1ρ' depending on the data type.
Equation for No Exchange in CPMG
[math] R_{2,\textrm{eff}} = R_2^0 [/math]
Equation for No Exchange in R1rho
[math] \mathrm{R}_{1\rho}= \mathrm{R}_1\cos^2\theta + \mathrm{R}_{1\rho}{´} \sin^2\theta [/math]
If no R1 values has been loaded, but the R1_fit flag has been turned on, the R1 will be fitted as well.
For data without a loaded offset, (see also relax disp.spin lock offset+field ), if
[math]
\bar{\Omega}_{S,i} = 0.0
[/math]
then the Rotating frame tilt angle θ is set to:
[math]
\theta = \frac{\pi}{2}
[/math]
and as such
[math]
cos^2\theta = cos^2\left( \frac{\pi}{2} \right) = 0.0
[/math]
Therefore the fitted R1 values have no meaning for "No Rex" model, if there is no offset.
Reference
These is no reference for the No Rex model.
Links
The implementation of the No Rex model in relax can be seen in the:
